Confirmation by IR of the preferred conformations of CFTA esters in solution: a highly reliable criterion for the stereochemistry assignment of chiral alcohols.
نویسندگان
چکیده
Direct confirmation of the preferred conformation of diastereomeric esters derived from a chiral secondary alcohol and a chiral derivatizing agent in solution, which is crucial for reliable NMR-based assignment of absolute stereochemistry of the alcohol, has been attained for the first time by examination of IR spectra of the CFTA esters.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 46 20 شماره
صفحات -
تاریخ انتشار 2010